Handbook of Biochemistry

Section C Lipids Carbohydrates & Steroids, Volume l

Gerald D Fasman

• Publisher: CRC Press
• Year: 2019
• ISBN:
  9780429945533
• Edition: 1
• Topic: Médecine
• Subtopic: Biochimie en médecine

This first volume contains data on amino acids which consists of the coefficients of solubility in water, heat capacities, entropies of formation, and heats of combustion. Specific gravity liquids, sucrose solution, CsCI solution isokinetic glycerol and sucrose gradients for density gradient centrifugation and the temperature dependence for select compounds are included.

Carbohydrates

Table 1
NATURAL ALDITOLS, INOSITOLS, INOSOSES, AND AMINO ALDITOS AND INOSAMINES

^a In order of increasing carbon chain length in the parent compounds grouped in the classes-alditols, inositols, inososes, amino alditols, and inosamines.

^b [α]_D for 1–5 g solute, c, per 100 ml aqueous solution at 20–25°C, unless otherwise given.

^c References for melting point and specific rotation data. Letter indicates the reference also has chromatographic data according to: c = column, e = electrophoresis, g = gas, p = paper, and t = thin-layer.

^d R value times 100, given relative to that of the compound indicated by abbreviation: f = solvent front, ala = alanine, ara = arabinose, asa = ascorbic acid, Cl = chloride ion, eic = eicosane, gain = galactono-1,4-lactone, galU = galacturonic acid, glc = glucose, glcN = glucosamine, glcU = glucuronic acid, gNAc = 7V-acetyl-glucosamine, gNUA = glucosaminuronic acid, kdh= 3-deoxy-erythro-hexulosonic acid, kdo= 3-deoxy-mtfw«o-octulosonicacid, kgu = 2-keto-gulonic acid, mal = malonic acid, manU = mannuronic acid, myo = myo-inositol, myot = myo-inositol trimethylsilyl ether, MU = methylene standard hydrocarbon units, nana = W-acetyl-neuraminic acid, pa = picric acid, rha = rhamnose, tmg = 2,3,4,6-tetra-O-methyl glucose, and xyll = xylitol pentamethylether. Under gas chromatography (column Glc or G) numbers without code indications signify retention time in minutes. The conditions of the chromatography are correlated with the reference given in parentheses and are found in Table 5.

^e said to exit as a phosphate ester also.¹⁰

^f Data given are for the enanthiomorphic isomer.

^g The author name as 3-dehydroquinic acid, but it is actually 5-dehydroquinic.

^h The early given name, 1-quercitol, of this compound does not make it the enanthiomorph of d-quercitol; other isomeric relations are involved.

ⁱ This compound is isomeric with the previous one in regard to the N-methy)group position.

Compiled by George G. Maher.

REFERENCES

1. Pollock and Stevens, Dictionary of Organic Compounds, Oxford University Press, New York, 1965.

2. Frahn and Mills, Aust. J. Chem., 12, 65 (1959).

3. Dooms, Declerck, and Verachtert, J. Chromatogr., 42, 349 (1969).

4. Bourne, Lees, and Weigel, J. Chromatogr., 11, 253 (1963).

5. de Simone and Vicedomini, J. Chromatogr., 37, 538 (1968).

6. Sawardeker, Sloneker, and Jeanes, Anal. Chem., 37, 1602 (1965).

7. Whyte, J. Chromatogr., 87, 163 (1973).

8. Roberts, Johnston, and Fuhr, Anal. Biochem., 10, 282 (1965).

9. Dutton and Unrau, Can. J. Chem., 43, 924, 1738 (1965).

10. Lindberg, Ark. Kemi. Mineral Geol., 23, A 2 (1946–1947).

11. Weatherall, J. Chromatogr., 26, 251 (1967)...

Table of contents

• Cover
• Half Title
• Title Page
• Copyright Page
• Dedication
• Table of Contents
• NOMENCLATURE
• CARBOHYDRATES
• LIPIDS
• STEROIDS
• INDEX