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Progress in Inorganic Chemistry, Volume 59
About This Book
This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 59 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers.
The chapters of this volume are devoted to the following topics:
ā¢Iron Catalysis in Synthetic Chemistry
ā¢A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites
ā¢Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA.
ā¢Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide
ā¢Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity
ā¢Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals
ā¢Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations
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Iron Catalysis in Synthetic Chemistry
- I. Introduction
- II. Addition Reactions
- A. Cycloadditions
- 1. The [2 + 2] Cycloaddition
- 2. The [3 + 2] Cycloaddition
- 3. The [2 + 2 + 2] Cycloaddition
- 4. The [4 + 2] Cycloaddition
- B. Cyclopropanation
- C. Aziridination and Aziridine Ring-Opening Reactions
- D. Carbometalation of CāC Unsaturated Bond
- E. Michael Addition
- F. Barbier-Type Reaction
- G. Kharasch Reaction
- A. Cycloadditions
- III. The CāC Bond Formations VIA CāH Functionalization
- A. The CāH Arylation
- 1. Direct Arylation With Organometallic Reagents
- 2. Direct Arylation With Aryl Halides
- B. The CāC Bond Formation Via Cross-Dehydrogenative Coupling
- 1. The CDC Between Two sp3 CāH Bonds
- 2. The CDC Between sp3 and sp2 CāH Bonds
- 3. The CDC Between sp3 and sp CāH Bonds
- C. The CāC Bond Formation via Cross-Decarboxylative Coupling
- D. The CāC Bond Formation via Alkene Insertion
- E. Oxidative Coupling of Two CāH Bonds
- A. The CāH Arylation
- IV. The CāH Bond Oxidation
- A. Hydroxylation
- B. Epoxidation
- C. cis-Dihydroxylation
- V. Cross-Coupling Reactions
- A. Alkenyl Derivatives as Coupling Partners
- B. Aryl Derivatives as Coupling Partners
- C. Alkyl Derivatives as Coupling Partners
- 1. Low-Valent Iron Complex in Cross-Coupling Reactions
- D. Acyl Derivatives as Coupling Partners
- E. Iron-Catalyzed CāO, CāS, and CāN Cross-Coupling Reaction
- F. Iron-Catalyzed MizorakiāHeck Reaction
- G. Iron-Catalyzed Negishi Coupling Reaction
- H. SuzukiāMiyaura Coupling Reaction
- I. Sonogashira Reaction
- J. Mechanism of Cross-Coupling Reactions
- K. Hydrocarboxylation
- L. Enyne Cross-Coupling Reaction
- VI. Direct CāN Bond Formation VIA CāH Oxidation
- VII. Iron-Catalyzed Amination
- A. Allylic Aminations
- B. Intramolecular Allylic Amination
- VIII. Sulfoxidations and Synthesis of Sulfoximines, Sulfimides, and Sulfoximides
- A. Sulfoxidation
- B. Synthesis of Sulfoximines, Sulfimides, and Sulfoximides
- 1. Mechanism
- IX. Reduction Reactions
- A. Hydrosilylation of Alkenes
- B. Hydrosilylation of Aldehydes and Ketones
- C. Hydrogenation of CāC Unsaturated Bonds
- D. Hydrogenation of Ketones
- E. Hydrogenation of Imines
- F. Reduction of Nitroarene to Anilines
- G. Hydrogenation of Carbon Dioxide and Bicarbonate
- H. Amide Reduction
- I. Reductive Aminations
- X. Trifluoromethylation
- XI. Conclusion
- Acknowledgments
- Abbreviations ...
Table of contents
- Cover
- Advisory Board
- Title Page
- Copyright
- Chapter 1: Iron Catalysis in Synthetic Chemistry
- Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites
- Chapter 3: Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA
- Chapter 4: Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide
- Chapter 5: Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity
- Chapter 6: Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals
- Chapter 7: Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations
- Subject Index
- Cumulative Index
- End User License Agreement