1
Introduction to Superconductivity
1.1 Basic Properties
The universally known fact about superconductivity is that below some characteristic transition temperature (Tc) many metals exhibit a complete lack of electrical resistance to a flow of direct current. Such a lossless āsupercurrentā can be set up around a closed loop of superconducting wire, there being no detectable decay with time (with a half-life shown experimentally to be at least 106 years).
This complete loss of resistance was first observed by Onnes (1911) for the metal mercury for which Tc = 4.19 K, close to the normal boiling point of liquid helium. The latter had been liquefied for the first time only shortly before in the same laboratory, thus opening up a new field of cryogenics.
1.1.1 Materials exhibiting superconductivity
Up to the present some 28 out of the 75 metallic elements have been shown to exhibit zero resistance with transition temperatures ranging from 0.005 K for rhodium up to 9.2 K for niobium. There are a vast number of alloy and compound superconductors. At the time of writing the highest known Tc is 125 K for a perovskite structured ternary oxide of thallium, calcium, barium and copper (see Chapter 9). The current frenetic activity to raise Tc to as high a value as possible is linked to the reduced cost of refrigeration which this would incur, and hence to a far greater application of superconducting devices in the world outside of research laboratories. Many other materials also exhibit superconductivity, including a number of non-metallic compounds and some organic salts, a few of which have Tcās which only a few years ago would have been regarded as remarkable. At the time of writing these have no apparent practical potential, although they reflect clearly the increasingly widespread but complex nature of the superconducting state.
1.1.2 Critical magnetic fields
From the earliest years the remarkable properties of superconductors have led to many proposed applications of the effects. Onnes himself suggested that high-field magnets having zero electrical losses could be made using superconductors. However the loss-free current-carrying capability of all these materials is very dependent on magnetic field, as well as on temperature. Above some critical field Hc, characteristic of the material and temperature, superconductivity is destroyed. The field generated by a current flowing in the superconductor itself must also be considered, so that even in zero external magnetic field there is a maximum supercurrent which can flow. This is a function of geometry as well as temperature and material. Onnesā original hopes for high-field solenoids took many years to realise, as the critical fields of elemental superconductors are too low to be useful. Amongst these the highest occurs for the element niobium, with a value of around 0.2 T, a factor of at least ten less than can be achieved with iron-cored solenoids.
1.1.3 Large-scale and high magnetic field applications
Some 50 years after Onnesā discovery a number of practically useful alloy superconductors, mainly based on niobium, began to be developed. These alloys have critical fields as great as 40 T, sufficient to replace high-field conventional solenoids, since the extra cost of refrigeration etc is far outweighed by the cost of power consumption through ohmic losses in normal metal coils.
As well as providing a reduction of power consumption, superconducting magnets are also able to provide very spatially and temporally stable magnetic fields. Superconducting solenoids may be operated in the āpersistent modeā, in which the ends of the windings are joined so that no external current source is required. The stability of high magnetic fields produced by the best persistent supercurrent solenoids has been shown to be better than 1 part in 1010 per hour (Petley 1989). The ability to use much higher current densities in superconducting magnets means that solenoid windings may be tailored to produce fields which are extremely spatially uniform (to better than 1 in 108 over a volume of 10ā6 m3).
Apart from magnets, superconducting windings may also be used to improve the efficiency of motors and generators. A limited number of pilot applications of this kind have already been demonstrated. A further expansion of these āelectrical engineeringā applications will probably not happen unless and until there is a new round of construction of even larger electrical generating sets. The subject of this book is āsuperconducting electronicsā, dealing with devices that rely entirely on the extreme sensitivity of superconducting circuits to very low magnetic fields. Such applications do not require vast capital investment and hence may be expected to proceed to expand in a steady way.
Superconductors are not truly lossless in applied alternating electromagnetic fields. In addition to being a strong function of temperature, particularly in the region from Tc down to roughly Tc/3, the losses are also a rapidly increasing function of frequency of the applied oscillating field. āPassiveā AC applications of superconductivity, which rely only on low-loss properties, have so far been limited to high-Q microwave cavities. These have been used as frequency standards, narrow band filters and, in higher-power operations, as components in particle accelerators.
1.2 The Meissner Effect
Applications of superconductivity of the electrical engineering type outlined above depend wholly on the property of zero electrical resistance. In fact, superconductivity ...