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Characterization of Porous Solids
About This Book
The importance of porosity has long been recognized by scientists and engineers. Porous solids are widely encountered in industry and everyday life and their behaviour, e.g. chemical reactivity, adsorptive capacity, and catalytic activity is dependent on their pore structure. A considerable amount of work on porous solids has been undertaken both in academic and in industrial laboratories. However, all this activity is in urgent need of a critical appraisal. To undertake this task, a number of leading experts in the field of adsorption, porosimetry, X-ray and neutron scattering, optical and electron microscopy, calorimetry and fluid permeation, were brought together at the 1987 IUPAC (COPS I) Symposium.This proceedings volume provides an up-to-date overall review of the theoretical foundations for modelling and characterizing porous systems. It deals with most of the techniques in current use as applied to both model systems and porous solids of industrial importance. The reader will find the description and discussion of a number of novel techniques as well as a critical appraisal and comparison of the more established methods. All those concerned with the characterization of porous solids in academic and industrial laboratories will find much to interest them in this volume. It should be on the bookshelf of applied research centres involved in adsorption, catalysis, purification of gases and liquids, pigments, fillers, building materials, etc.
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Table of contents
- Front Cover
- Characterization of Porous Solids
- Copyright Page
- Contents
- Preface
- Chapter 1. Pore systems and their characteristics
- Chapter 2. Neutron scattering from porous solids
- Chapter 3. Small-angle scattering studies of porous solids
- Chapter 4. Characterization of active carbons from palm-tree fibers using nitrogen adsorption and small angle X-ray scattering
- Chapter 5. A comparison of nitrogen adsorption, small angle neutron scattering and TEM techniques for characterisation of mesoporous oxides
- Chapter 6. A critical assessment of quasi-equilibrium gas adsorption techniques in volumetry, gravimetry or calorimetry
- Chapter 7. Assessment of microporosity
- Chapter 8. A new method for the determination of micropore size distributions
- Chapter 9. Sorption studies on large ZSM-5 crystals: the influence of aluminium content the type of exchangeable cations and the temperature on nitrogen hysteresis effects
- Chapter 10. Cell-theoretical and molecular-statistical treatment of the pore filling of pentasil-type zeolites by benzene molecules
- Chapter 11. Characterization of microporous catalysts by N2 adsorption: empirical correlations between parameters assessed by different methods
- Chapter 12. Characterisation of adsorption properties and microporous structures of carbonaceous adsorbents
- Chapter 13. Microporosity in carbonaceous materials: development surface composition and characterization
- Chapter 14. Characterisation of adsorption on microporous carbons using the generalised adsorption isotherm
- Chapter 15. Influence of exchangeable anions on the accessability of micropores in activated carbons
- Chapter 16. Carbon dioxide subtraction (CDS) method applied to a wide range of porous carbons
- Chapter 17. Anomalous micropore filling of NO on Fe2O3-dispersed activated carbon fibers
- Chapter 18. The volume of small micropores in unmodified, oxidized or irradiated graphitic matrix
- Chapter 19. Hysteresis effects in the high-pressure adsorption of gases in graphite foam (GRAFOAM)
- Chapter 20. Estimation of surface and structural heterogeneity of microporous carbons from gas adsorption data
- Chapter 21. Determination of mesopores diameters in porous solids from adsorption measurements – criticisms and suggestions
- Chapter 22. The generalized Broekhoff-De Boer method
- Chapter 23. Capillary properties of pores formed by two unequal parallel rods and a plate
- Chapter 24. Characterization of petroleum reservoir rocks by capillary pressure techniques
- Chapter 25. The porosity of samples of the disperse dye, C.I. Disperse Blue 79
- Chapter 26. Measurement of the morphology of high surface area solids: inferring pore shape characteristics
- Chapter 27. Computer driven porosimeter for ultrafiltration membranes
- Chapter 28. The role of thermoporometry in the study of porous solids
- Chapter 29. Progress in thermoporometry
- Chapter 30. Information brought by adsorption and immersion microcalorimetry to follow the porous structure of sepiolite during its thermal treatment
- Chapter 31. Porous materials and percolation theory
- Chapter 32. Characterization of catalyst pore structure by parameters describing mass transport
- Chapter 33. Macrodescription of micropore structure in regard to fluid flow through porous media
- Chapter 34. Sorption and diffusion of benzene and xylenes in zeolite ZSM-5: diffusion anomalies and hysteresis effects
- Chapter 35. Non-isothermal sorption kinetics and NMR diffusion studies: fundamental problems of molecular transport in porous materials
- Chapter 36. Studies on diffusion of phenols within a porous synthetic adsorbent
- Chapter 37. Analysis of pore structure via spin-lattice relaxation measurements
- Chapter 38. Relative gas permeability properties of model pore networks
- Chapter 39. Permeation through zeolite filled silicone rubber membranes
- Chapter 40. The fractal nature of molecule-surface chemical activities and physical interactions in porous materials
- Chapter 41. Hydrodynamic transport in and around fractal porous media
- Chapter 42. Determination of the fractal dimension of aggregates using the intra-aggre gate pore-size distribution
- Chapter 43. Fractal flow patterns in porous media
- Chapter 44. Interferometric determination and fractal characterization of gel porosity
- Chapter 45. Relations between physically relevant geometrical properties of a multifractal porous system
- Chapter 46. Adsorption of carbon dioxide. benzene, nitrogen and argon by microporous carbons: interpretation of isotherms and enthalpies of adsorption and immersion
- Chapter 47. Routine analysis of the pore structure of mesoporous and macroporous solids by gas adsorption, mercury porosimetry and densitometry
- Chapter 48. Comparison of results from nitrogen adsorption and mercury penetration for spherical-particle carbon blacks
- Chapter 49. Pore structure analysis of American coals
- Chapter 50. Size, shape and site selectivities in the photochemical reactions of molecules adsorbed or pentasil zeolites
- Chapter 51. Characterization of the effective pore width of molecular sieve solids by means of catalytic test reactions
- Chapter 52. Modified aluminophosphate microporous solids
- Chapter 53. Characterization of the secondary pore system in dealuminated HY zeolites: comparison between isomorphous substitution and hydrothermal treatment
- Chapter 54. Aclay-based support with high porosity for HDM-catalyst
- Chapter 55. Preparation and properties of copper synthetic anionic clays
- Chapter 56. Investigations on the micro-structure of hardened cement pastes
- Chapter 57. Texture evolution of sulphurized natural and acid treated bentonites
- Chapter 58. The influence of preparation methods on surface area, porosity and crystallinity of magnesium oxide
- Chapter 59. Effect of warm and dry curing on the pore structure of cement-lime mortar
- Chapter 60. The preparation and characterization of porous silica spheres of a controlled texture
- Chapter 61. Structural, elasto-mechanical and thermal properties of silica aerogels
- Chapter 62. Adsorption of albumin to porous silicas
- Studies in Surface Science and Catalysis