Mixed-Valence Systems: Fundamentals, Synthesis, Electron Transfer, and Applications covers all topics related to the theory and experimental results of mixed-valence systems, including the design, synthesis, and applications of mixed-valence compounds containing inorganic, organometallic and organic redox-active centers. The text also covers the recent advances in mixed-valence chemistry, including the development of new mixed-valence systems, transition of mixed valency, better understanding of the spectral characteristics of intervalence charge transfer, and controllable electron transfer related to molecular electronics.

In Mixed-Valence Systems, readers can expect to find detailed information on sample topics such as:

Characterization and evaluation of mixed-valence systems, electron paramagnetic resonance spectroscopy, and electrochemical methods
Optical analysis, important issues in mixed-valence chemistry, transition of mixed valency from localized to delocalized, and solvent control of electron transfer
Theoretical background, potential energy surfaces from classical two-state model, and quantum description of the potential energy surfaces
Reorganization energies, electronic coupling matrix element and the transition moments, generalized Mulliken–Hush theory, and analysis of the band shape of intervalence charge transfer

Strengthening the relationship of mixed-valence electron transfer and molecular electronics, Mixed-Valence Systems is of immense value to researchers and professionals working in the field of electron transfer, molecular electronics, and optoelectronics.

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Yes, you can access Mixed-Valence Systems by Yu-Wu Zhong,Chun Yuan Liu,Jeffrey R. Reimers in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Inorganic Chemistry. We have over one million books available in our catalogue for you to explore.

Information

Publisher

Wiley-VCH

Year

2023

ISBN

9783527835270

Edition

Topic

Physical Sciences

Subtopic

Inorganic Chemistry

Cover
Table of Contents
Title Page
Copyright
Dedicated to Noel S. Hush AO FAA FRS (1924–2019)
Preface
1 Introduction and Fundamentals of Mixed-Valence Chemistry
2 Conceptual Understanding of Mixed-Valence Compounds and Its Extension to General Stereoisomerism
3 Quantum Chemical Approaches to Treat Mixed-Valence Systems Realistically for Delocalized and Localized Situations
4 Mixed Valency in Ligand-Bridged Diruthenium Complexes
5 Electronic Communication in Mixed-Valence (MV) Ethynyl, Butadiynediyl, and Polyynediyl Complexes of Iron, Ruthenium, and Other Late Transition Metals
6 Electron Transfer in Mixed-Valence Ferrocenyl-Functionalized Five- and Six-Membered Heterocycles
7 Electronic Coupling and Electron Transfer in Mixed-Valence Systems with Covalently Bonded Dimetal Units
8 Mixed-Valence Electron Transfer of Cyanide-Bridged Multimetallic Systems
9 Organic Mixed-Valence Systems: Toward Fundamental Understanding of Charge/Spin Transfer Materials
10 Mixed-Valence Complexes in Biological and Bio-mimic Systems
11 Control of Electron Coupling and Electron Transfer Through Non-covalent Interactions in Mixed-Valence Systems
12 Stimulus-Responsive Mixed-Valence and Related Donor–Acceptor Systems
13 Mixed Valency in Extended Materials
14 Near-Infrared Electrochromism Based on Intervalence Charge Transfer
15 Manipulation of Metal-to-Metal Charge Transfer Toward Switchable Functions
Index
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