Basic Organometallic Chemistry

Ionel Haiduc, Jerry J. Zuckerman

• Publisher: De Gruyter
• Year: 2011
• ISBN:
  9783110847888
• Edition: 1
• Topic: Physical Sciences
• Subtopic: Chemistry
• Index: Chemistry

No detailed description available for "Basic Organometallic Chemistry".

Table of contents

• Part I
• 1. Introduction
• 1.1. The Scope of Organometallic Chemistry
• 1.2. Some Historical Notes
• 1.3. The Classification of Organometallic Compounds
• 2. The Metal-Carbon Bond
• 2.1 Bond Types
• Ionic Bonds
• Sigma Covalent Bonds (Bicentric Bielectronic)
• Electron-Deficient Bonds (Localized Polycentric Bonds)
• Delocalized Bonds in Polynuclear Systems
• Dative Bonds, with d-Orbital participation (Sigma Donor - Pi Acceptor)
• 2.2. Metal-Carbon Ionic Bonds
• 2.3. Sigma (σ ) Covalent Bonds (Bicentric Bielectronic)
• 2.4. Electron-Deficient Bonds (Polycentric Localized-Bonds)
• 2.5. Delocalized Bonds in Polynuclear Systems
• 2.6. Dative Bonds with Participation of d-Orbitals
• 3. Laboratory Techniques in Organometallic Chemistry
• 3.1. Synthesis and Isolation of Compounds
• 3.2. Analysis and Structural Characterization
• 4. The Literature of Organometallic Chemistry
• 4.1. Textbooks and General Monographs
• 4.2. Reviews
• 4.3. Primary Literature
• Part II Organometallic Compounds of Non-Transition Elements
• 5. Organometallic Compounds of Alkali Metals
• 5.1. Organolithium Compounds
• 5.2. Organometallic Derivatives of Sodium and the Heavier Alkali Metals
• 6. Organometallic Compounds of the Group II Elements
• 6.1. Organoberyllium Compounds
• 6.2. Organomagnesium Compounds
• 6.3. Organometallic Compounds of Calcium, Strontium and Barium
• 6.4. Organozinc Compounds
• 6.5. Organocadmium Derivatives
• 6.6. Organomercury Compounds
• 7. Organometallic Compounds of Group III A Elements
• 7.1. Organoboron Compounds
• 7.2. Organoaluminum Compounds
• 7.3. Organogallium Compounds
• 7.4. Organoindium Compounds
• Trisubstituted Derivatives, InR3
• Diorganoindium Halides, R2InX
• Organoindium Dihalides, RInX2
• 7.5. Organothallium Compounds
• 8. Organometallic Compounds of Group IVA Elements
• 8.1. Organosilicon Compounds
• 8.2. Organogermanium Compounds
• 8.3. Organotin Compounds
• 8.4. Organolead Compounds
• 9. Organometallic Compounds of Group VA Elements
• 9.1. Organoarsenic Compounds
• 9.2. Organoantimony Compounds
• 9.3. Organobismuth Compounds
• Part III Organometallic Compounds of Transition Metals
• 10. The Electronic Structure and Classification of Transition-Metal Organometallic Compounds
• 10.1 The Transition Metals
• 10.2. The Ligands
• 11. Compounds with Two-Electron Ligands
• 11.1. Metal Carbonyls
• 11.2. Metal Thiocarbonyls
• 11.3. Metal Selenocarbonyls
• 11.4. Metal-Isocyanide Complexes
• 11.5. Metal-Carbene Complexes and Related Compounds
• 11.6. π -Olefinic Complexes
• 12. Compounds with Three-Electron Ligands
• 12.1. π -Allylic Complexes and Related Compounds
• Scandium, Lanthanides, Actinides
• Titanium, Zirconium, Hafnium
• Vanadium, Niobium, Tantalum
• Chromium, Molybdenum, Tungsten
• Manganese, Technetium, Rhenium
• Iron, Ruthenium, Osmium
• Cobalt, Rhodium, Iridium
• Nickel, Palladium, Platinum
• 12.2. Cyclopropenyl Complexes
• 12.3. Metal-Carbyne Complexes
• 13. Compounds with Four-Electron Ligands
• 13.1. Butadiene Complexes and Related Compounds
• 13.2. Cyclobutadiene Complexes
• 13.3. η 4-Complexes of Cyclopentadiene, Cyclopentadienone, Fulvene and Heterocycles Derived from Cyclopentadiene
• Cyclopentadiene
• Cyclopentadienones
• Fulvenes
• Heterocycles
• 13.4. Complexes with Other Cyclic Dienes and Polyenes
• Cyclohexadiene-1,3
• Cycloheptadiene-1,3
• Cycloheptatriene-1,3,5
• Cyclooctatetrane
• 13.5. Trimethylenemethyl Complexes
• 13.6. Boron-Containing Four-Electron Ligands
• 14. Compounds with Five-Electron Ligands
• 14.1. Transition Metal, η 5-Cyclopentadienyl Complexes
• Scandium, Yttrium, Lanthanides and Actinides. (Group III Elements)
• Titanium, Zirconium, Hafnium
• Vanadium, Niobium, Tantalum
• Chromium, Molybdenum, Tungsten
• Manganese, Technetium, Rhenium
• Iron, Ruthenium, Osmium
• Cobalt, Rhodium, Iridium
• Nickel, Palladium, Platinum
• Copper, Silver, Gold
• 14.2. Acyclic Pentadienyl η 5-Complexes
• 14.3. η 5-Complexes of Some Heterocyclic Ligands
• 14.4. η 5-Cyclohexadienyl Complexes
• 14.5. η 5-Cycloheptadienyl Complexes
• 14.6. Complexes of Carborane Ligands
• 15. Compounds with Six-Electron Ligands
• 15.1. η 6-Complexes of Benzene and its Derivatives
• Titanium, Zirconium, Hafnium
• Vanadium, Niobium, Tantalum
• Chromium, Molybdenum, Tungsten
• Manganese, Technetium, Rhenium
• Iron, Ruthenium, Osmium
• Cobalt, Rhodium, Iridium
• 15.2 η 6-Cycloheptatriene Complexes
• 15.3. Cyclooctatriene and Cyclooctatetraene as Six-Electron Ligands
• 15.4. Some η 6-Complexes with Heterocyclic Ligands
• 16. Compounds with Seven- and Eight-Electron Ligands
• 16.1. Seven-Electron Ligands
• 16.2. Eight-Electron Ligands
• 17. Organometallic Compounds Derived from Acetylenes
• 17.1. Complexes of Untransformed Acetylenes as Terminal (Dihapto) Ligands
• Titanium, Zirconium, Hafnium
• Vanadium, Niobium, Tantalum
• Chromium, Molybdenum, Tungsten
• Manganese, Technetium, Rhenium
• Iron, Ruthenium, Osmium
• Cobalt, Rhodium, Iridium
• Nickel, Palladium, Platinum
• 17.2. Binuclear Complexes with Bridging Acetylene Ligands
• 17.3. Compounds Incorporating the Acetylene in a Polynuclear Cluster
• 17.4. Complexes Formed by Chemical Transformations of Acetylenes
• 18. Organometallic Compounds with σ -Metal-Carbon Bonds
• Scandium, Yttrium, Lanthanides and Actinides (Group IIIB Elements)
• Titanium, Zirconium, Hafnium
• Vanadium, Niobium, Tantalum
• Chromium, Molybdenum, Tungsten
• Manganese, Technetium, Rhenium
• Iron, Ruthenium, Osmium
• Cobalt, Rhodium, Iridium
• Nickel, Palladium, Platinum
• Copper, Silver, Gold
• Bibliography
• Subject Index