Alkane Functionalization

Armando J. L. Pombeiro, Maria de Fatima Costa Guedes da Silva

• Publisher: Wiley
• Year: 2018
• ISBN:
  9781119379249
• Edition: 1
• Topic: Ciencias físicas
• Subtopic: Química orgánica

Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes

Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes.

The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource:

• Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes
• Contains information from leading experts on the topic
• Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes
• Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds

Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.

Table of contents

• Cover
• Table of Contents
• List of Contributors
• About the Editors
• Preface
• List of Abbreviations
• 1 Alkane Functionalization: Introduction and Overview
• CO Bond Formation. Hydroxylation and Other Oxygenation Reactions
• Bioinspired Alkane Functionalization
• CB, CC and CN Bond Formation
• Dehydrogenation Reactions
• Unconventional Systems
• Index
• End User License Agreement