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Organic Reaction Mechanisms 2013
An annual survey covering the literature dated January to December 2013
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eBook - ePub
Organic Reaction Mechanisms 2013
An annual survey covering the literature dated January to December 2013
Book details
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Table of contents
Citations
About This Book
Organic Reaction Mechanisms 2013, the 49th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2013.
The following classes of organic reaction mechanisms are comprehensively reviewed:
- Reaction of Aldehydes and Ketones and their Derivatives
- Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
- Oxidation and Reduction
- Carbenes and Nitrenes
- Nucleophilic Aromatic Substitution
- Electrophilic Aromatic Substitution
- Carbocations
- Nucleophilic Aliphatic Substitution
- Carbanions and Electrophilic Aliphatic Substitution
- Elimination Reactions
- Polar Addition Reactions
- Cycloaddition Reactions
- Molecular Rearrangements
An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation.
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Information
Chapter 1
Reactions of Aldehydes and Ketones and Their Derivatives
B. A. Murray
Department of Science, Institute of Technology, Tallaght (ITT Dublin), Dublin, Ireland
- Formation and Reactions of Acetals and Related Species
- Reactions of Glucosides
- Reactions of Ketenes
- Formation and Reactions of Nitrogen Derivatives
- Imines: Synthesis, and General and Iminium Chemistry
- Mannich, Mannich-type and Nitro-Mannich Reactions
- Other âNameâ Reactions of Imines
- Synthesis of Azacyclopropanes from Imines
- Alkylations and Additions of Other C-Nucleophiles to Imines
- Arylations, Alkenylations and Allylations of Imines
- Miscellaneous Additions to Imines
- Reduction of Imines
- Other Reactions of Imines
- Oximes, Hydrazones and Related Species
- CâC Bond Formation and Fission: Aldol and Related Reactions
- Reviews of Aldols and General Reviews of Asymmetric Catalysis
- Asymmetric Aldols Catalysed by Proline and Its Derivatives
- Asymmetric Aldols Catalysed by Other Organocatalysts
- The Mukaiyama Aldol
- Other Asymmetric Aldols
- The Henry (Nitroaldol) Reaction
- The BaylisâHillman Reaction and Its Morita-variant
- Other Aldol and Aldol-type Reactions
- Allylation and Related Reactions
- The HornerâWadsworthâEmmons Reaction and Related Olefinations
- Alkynylations
- Stetter Reaction, Benzoin Condensation and Pinacol Coupling
- Michael Additions
- Miscellaneous Condensations
- Other Addition Reactions
- Addition of Organozincs
- Arylations
- Addition of Other Organometallics
- The Wittig Reaction
- Hydrocyanation, Cyanosilylation and Related Additions
- α-Aminations and Related Reactions
- Miscellaneous Additions
- Enolization, Reactions of Enolates and Related Reactions
- α-Halogenation, α-Alkylation and Other α-Substitutions
- Oxidation and Reduction of Carbonyl Compounds
- Oxidation of Aldehydes to Acids
- Oxidation of Aldehydes to Amides, Esters and Related Functional Groups
- BaeyerâVilliger and Other Oxidation Reactions of Ketones
- Miscellaneous Oxidative Processes
- Reduction Reactions
- Stereoselective Reduction Reactions
- Other Reactions
- References
Formation and Reactions of Acetals and Related Species
Equilibria for the formation of hemiacetals from eight isomeric hexanals have been measured in methanol, and compared with the steric environment around the aldehyde.1 Kinetic studies have also been carried out, and these suggest an early TS.
Table of contents
- Cover
- Title Page
- Copyright
- Table of Contents
- Contributors
- Preface
- Chapter 1: Reactions of Aldehydes and Ketones and Their Derivatives
- Chapter 2: Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and Their Derivatives
- Chapter 3: Oxidation and Reduction
- Chapter 4: Carbenes and Nitrenes
- Chapter 5: Aromatic Substitution
- Chapter 6: Carbocations
- Chapter 7: Nucleophilic Aliphatic Substitution
- Chapter 8: Carbanions and Electrophilic Aliphatic Substitution
- Chapter 9: Elimination Reactions
- Chapter 10: Addition Reactions: Polar Addition
- Chapter 11: Addition Reactions: Cycloaddition
- Chapter 12: Molecular Rearrangements
- Author Index
- Subject Index
- End User License Agreement