Organic Reaction Mechanisms 2012, the 48th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2012. The following classes of organic reaction mechanisms are comprehensively reviewed:
Reaction of Aldehydes and Ketones and their Derivatives
Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
Oxidation and Reduction
Carbenes and Nitrenes
Nucleophilic Aromatic Substitution
Electrophilic Aromatic Substitution
Carbocations
Nucleophilic Aliphatic Substitution
Carbanions and Electrophilic Aliphatic Substitution
Elimination Reactions
Polar Addition Reactions
Cycloaddition Reactions
Molecular Rearrangements
An experienced team of authors compiled these reviews, ensuring the quality of selection and presentation.
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Yes, you can access Organic Reaction Mechanisms 2012 by A. C. Knipe in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Organic Chemistry. We have over one million books available in our catalogue for you to explore.
Chapter 1 Reactions of Aldehydes and Ketones and their Derivatives
A.C. Knipe
Faculty of Life and Health Sciences, University of Ulster, Coleraine, Northern Ireland
Formation and Reactions of Acetals and Related Species
Reactions of Glucosides and Nucleosides
Reactions of Ketenes and Ketenimines
Formation and Reactions of Nitrogen Derivatives
Imines: Synthesis, Tautomerism, and Catalysis
The Mannich and Nitro-Mannich reactions
Addition of organometallics
Other alkenylations, allylations, and arylations of imines
Oxidation and reduction of imines
Iminium species
Imine cycloadditions
Other reactions of imines
Oximes, Hydrazones, and Related Species
CâC Bond Formation and Fission: Aldol and Related Reactions
Reviews of Organocatalysts
Asymmetric Aldols Catalysed by Proline, Its Derivatives, and Related Catalysts
Other Asymmetric and Diastereoselective Aldols
Mukaiyama and Vinylogous Aldols
Other Aldol and Aldol-type Reactions
The Henry (Nitroaldol) Reaction
The BaylisâHillman Reaction and Its Morita Variant
Allylation and related reactions
Alkynylations
Michael Additions
Miscellaneous Condensations
Other Addition Reactions
Addition of Organozincs
Arylations
Addition of Other Organometallics, Including Grignards
The Wittig Reaction
Hydrocyanation, Cyanosilylation, and Related Additions
Hydrosilylation, hydrophosphonylation, and related reactions
Miscellaneous additions
Enolization and Related Reactions
Enolization
α-Alkylation, α-Halogenation, and Other α-Substitutions
Oxidation and Reduction of Carbonyl Compounds
Regio-, Enantio-, and Diastereo-selective Reduction Reactions
Other Reduction Reactions
Oxidation Reactions
Cycloadditions
Other Reactions
References
Formation and Reactions of Acetals and Related Species
Mechanisms and energetics for BrĂžnsted-acid-catalysed glucose condensations, dehydration, and isomerization reactions have been reviewed.1 Recent developments in the asymmetric synthesis of spiroketals have been reviewed and the potential for further application of transition metal catalysis and organocatalysis has been highlighted.2
Hemiacetal formation from formaldehyde and methanol has been studied by intrinsic reactivity analysis at the B3LYP/6-311++G(d,p) level and the beneficial combined assistance of watermolecules and BrĂžnsted acids has been quantified.3 Theoretical study of hemiacetal formation from methanol with derivatives of CH3CHO (X = H, F, Cl, Br, and I) has shown that the energy barrier can be reduced by a catalytic molecule (MeOH or hemiacetal product).4
A combined experimental and density functional theory (DFT) study of the thermal decomposition o...
Table of contents
Cover
Title Page
Copyright
Table of Contents
Contributors
Preface
Chapter 1: Reactions of Aldehydes and Ketones and their Derivatives
Chapter 2: Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
Chapter 3: Oxidation and Reduction
Chapter 4: Carbenes and Nitrenes
Chapter 5: Aromatic Substitution
Chapter 6: Carbocations
Chapter 7: Nucleophilic Aliphatic Substitution
Chapter 8: Carbanions and Electrophilic Aliphatic Substitution
