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About This Book
Covering the gap between basic textbooks and over-specialized scientific publications, this is the first reference available to describe this interdisciplinary topic for PhD students and scientists starting in the field. The result is an introductory description providing suitable practical examples of the basic methods used to study tautomeric processes, as well as the theories describing the tautomerism and proton transfer phenomena. It also includes different spectroscopic methods for examining tautomerism, such as UV-VIs, time-resolved fluorescence spectroscopy, and NMR spectroscopy, plus the theoretical and practical background information. With its excellent overview of the methods, theories and examples, this is the perfect guide for any scientist dealing with tautomeric compounds in a wider context.
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Table of contents
- Cover
- Related Titles
- Title Page
- Copyright
- Dedication
- Preface
- List of Contributors
- Chapter 1: Tautomerism: Introduction, History, and Recent Developments in Experimental and Theoretical Methods
- Chapter 2: Absorption UVâvis Spectroscopy and Chemometrics: From Qualitative Conclusions to Quantitative Analysis
- Chapter 3: Studies of Photoinduced NH Tautomerism by Stationary and Time-Resolved Fluorescence Techniques
- Chapter 4: Femtosecond PumpâProbe Spectroscopy of Photoinduced Tautomerism
- Chapter 5: NMR Spectroscopic Study of Tautomerism in Solution and in the Solid State
- Chapter 6: Isotope Effects on Chemical Shifts as a Tool in the Study of Tautomeric Equilibria
- Chapter 7: Tautomer-Selective Spectroscopy of Nucleobases, Isolated in the Gas Phase
- Chapter 8: Direct Evidence of Solid-State Tautomerism by Diffraction Methods: Isomers, Equilibria, and Kinetics
- Chapter 9: Dynamics of Ground- and Excited-State Intramolecular Proton Transfer Reactions
- Chapter 10: Force Field Treatment of Proton and Hydrogen Transfer in Molecular Systems
- Chapter 11: The Scope and Limitations of LSER in the Study of Tautomer Ratio
- Chapter 12: The âBasicity Methodâ for Estimating Tautomer Ratio: A Radical Re-appraisal
- Chapter 13: Quantum Chemical Calculation of Tautomeric Equilibria
- Index