Polymeric Foams

Innovations in Technologies and Environmentally Friendly Materials

S.-T. Lee, S.-T. Lee

• Publisher: CRC Press
• Year: 2022
• ISBN:
  9781000588736
• Edition: 1
• Topic: Technik & Maschinenbau
• Subtopic: Chemie- & Biochemietechnik

Polymeric Foams: Innovations in Technologies and Environmentally Friendly Materials offers the latest in technology and environmental innovations within the field of polymeric foams. It outlines how application-focused research in polymeric foam can continue to improve living quality and enhance social responsibility.

This book:

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• Addresses technological innovations including those in bead foams, foam injection molding, foams in tissue engineering, foams in insulation, and silicon rubber foam

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• Discusses environmentally friendly innovations in PET foam, degradable and renewable foam, and physical blowing agents

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• Describes principles as well as applications from internationally recognized foam experts

This work is aimed at researchers and industry professionals across chemical, mechanical, materials, polymer engineering, and anyone else developing and applying these advanced polymeric materials.

1 Introduction

Shau-Tarng Lee

Foam Update

DOI: 10.1201/9781003166160-1

Contents

• 1.1 Introduction
• 1.2 Innovations
  • 1.2.1 Polypropylene Foam Sheet
  • 1.2.2 Elastomeric Foam
• 1.3 Environment: Degradable and Renewable Foam
  • 1.3.1 Water-Soluble Foam
  • 1.3.2 Renewable-Source Foam
  • 1.3.3 Health Care
• 1.4 Machinery Advancement
  • 1.4.1 Cooling Design Progression for Foam Extrusion
  • 1.4.2 Pressure Mold Foaming for Engineered Polymers
• 1.5 Summary
• References

1.1 Introduction

Polymeric foams began its footprints in the 1930s in Europe. World War II greatly fueled technology advancements in machinery design, benefitting polymeric foam production. After the War, technology transfer to civilian applications along with significant research into the mysterious polymeric foam development made tremendous strides in the technology advancement [1,2]. Since then, business began to find in-roads into applications to improve living quality [3]. Figure 1.1 shows a photo of polystyrene (PS) foam log taken in 1949. In the 1960s, foam was recognized in the US and EU markets as a useful product for protection and packaging. The living standard improved. It drew R&D supports from industrial partners to excel manufacturing technology for sustainable business growth. A vivid business model was established. Meanwhile, Japan also joined the methodology development force, which became fruitful in the 1970s and thereafter [4]. The Microcellular technology and the Montreal Protocol to regulate emissions of halogenated hydrocarbon known as chlorofluorocarbon (CFC) were the major events in the 1980s [5,6 and 7]. The former simply opened the academic R&D gate to work closely with industrial R&D not only for business growth but social accountability. For plastics industry, recycle/reuse became a top concern in the 1990s, which was a tougher issue for foam, since it generally required a tighter processing window. When climate change drew global attention in the beginning of the twenty-first century, more pressure was laid on the plastic industry. Foam in food and beverage packaging has been switched to paper-based alternatives. At the same time, foam’s role began to change from visible core product to invisible supportive specialty material. Its consumption continues to increase as illustrated in Figure 1.2 [8]. A quick summary of the foam technology/business development for the last 90 years is provided in Table 1.1.

FIGURE 1.1 A woman holds a Styrofoam^® log in this 1949 photo. (Courtesy of Science History Institute.)

FIGURE 1.2 Low-Density Polymeric Foam Revenues, 1960–2200 [7]; copyright permission obtained.

TABLE 1.1 A Brief Summary of Technology/Business Development in Last 90 Years

Years	Technology	Product	Attribute	Application
1930	Reactive foaming	PU	Light & rigidity	Military
1940	Mold foaming	PS, PE	Shock absorption	Flotation
1950	Extrusion	PS	Thermoforming	Food, packaging
1960	X-linking, injection mold	PE	Soft & formable	Automotive
1970	Bead foaming	PS, c-PP	Irregular shape	Cup, packaging
1980	Microcellular	PS	Inorganic blowing agent	Food
1990	Extrusion	PET, PP	Branched polymer	Food, box
2000	Extrusion, molding	PLA	Renewable source	Food
2010	Nanocellular	PMMA	Low conductivity	Insulation- to be proved
2020	Mold foaming	TPU	Elasticity	Sports

In fact, polymer consumption for low-density foam—expansion over 15 times—is less than 10% by weight. Yet its expansion over 15 times—more areas over 20 times due to precision technology—makes it the most visible in the eyes of the consumer and in the waste management chain. The technology focus was turned from how to increase performance/weight ratio before the 1980s to how to reduce its life recycle and carbon footprint in the twenty-first century. From the trend, it is evident that the driving force began with technology optimization up to 1980, then business practice till 2000, and now to customer satisfaction. Innovative and socially accountable operation became the focal point. The merging between Exxon and Mobil in the 1990s and Dow and Dupont in 2016 are good illustrations. Innovation trends are simply turned from technical front to novel applications [9,10]. There is no doubt that innovation and environment are the main thrusts in the existing and new business development for foam. The encouraging part is that foam is not just for density reduction in the commodity markets, but its high internal surface area could be a useful characteristic in the sports, health care, medical, electronics, and cosmetics. Although foam may not be the core technology to promote other peripheral techniques into a solid platform to lead the society forward, transformation into the critical supportive role is crucial for foam to keep a sustainable growth.

By the end of the twentieth century, most foam technologies, such as foam extrusion, injection molding, bead foam, and x-linked foam, had a very solid foundation. There is not a question that innovative application and environmental merits became the main driver to make the foam product not only a performance material but with a social image in it. This chapter is to address the change in the last decade, when there are incremental improvement in foaming technology and expansion in the application spectrum. Figure 1.3 shows the application comparison between 2000 and 2020. Obviously, customers’ voice played a critical role two decades ago, yet mainly to benefit customers. Now social awareness becomes increasingly important. Social accountability simply raised the bar. The fundamental flow chart as illustrated in Figure 1.4 is the same, but global wellness and awareness continue to drive the demand.

FIGURE 1.3 Selected application items for performance foam between 2000 and 2020.

FIGURE 1.4 A simplified mapping of Knowledge-Technology-Business development with its characteristics.

1.2 Innovations

1.2.1 Polypropylene Foam Sheet

PS foam has been known for its wide processing window, high expansion, very good modulus, and excellent thermoformability. It dominated beverage cups, food container, and packaging industries for several decades. The annual consumption reached 120 thousand metric tons in the 1980s. It can be imagined that after 30 times expansion; it became the most visible foam product in the society. Since its decomposition by ultraviolet (UV) was so slow, when combined with its bulkiness, it became an easy target for the environmental group in the early 1990s. Request for alternatives began. Development of high-melt-strength polypropylene a...

Table of contents

• Cover
• Half Title
• Series Page
• Title Page
• Copyright Page
• Dedication Page
• Table of Contents
• Preface
• Biography
• Contributors
• Chapter 1 Introduction
• Chapter 2 Modification of Rheological Responses under Elongational Flow
• Chapter 3 Bead Foams
• Chapter 4 Foam Injection Molding
• Chapter 5 High-Pressure Foam Injection Molding of Polylactide/Nano-Fibril Composites with Mold Opening
• Chapter 6 Foams in Tissue Engineering
• Chapter 7 Foam in Insulation
• Chapter 8 Advancements in Foam Injection Molding
• Chapter 9 Silicone Foams: A World Different from Other Foams
• Chapter 10 Lab Analysis of Melt-Foaming Behaviors of Long-Chain Branched Polyethylene Terephthalate Using Supercritical CO2 as Blowing Agent
• Chapter 11 Extrusion Foam of Polylactic Acid Using Stereocomplex Crystals
• Chapter 12 Nanocellular Polymers
• Index